Biomolecules

Properties & Biological Importance of Vitamin K

One of the main importance of vitamin K helps with blood clotting, it is also called coagulation vitamin or antihemorrhagic factor. 

In 1929, a Danish investigator, Henrik Dam discovered that the chickens fed on an artificial diet suffered a haemorrhage due to prolonged periods of blood clotting. Later in 1934, he coined the term Vitamin K (k stands for Coagulation in Danish) for the vital compound that cured this condition.

Characteristics of Vitamin K

  • Vit K exists in two forms- Vit K1 and Vit K2 found in plants and animals, respectively.
  • Vit K1 is found in alfalfa, cabbage, spinach, etc.
  • Vit K2 is found in putrefied fish meal and intestinal bacteria.
  • Both types of Vit K are derivatives of quinones.
  • They differ in the side chain of Carbon 3 of naphthoquinone ring- Phytol radical in Vit K1 and farnesyl pyrophosphate in Vit K2.
  • Vit K1 also has 4 units of isoprene in its side chain whereas Vit K2 has 6 units of isoprene with a double bond in the side chain.

Properties of Vitamin K

  • Vitamin K1 appears as a yellow viscous oil while Vit K2 has the same color but is crystalline in form.
  • Both are sensitive to light and must be stored in the dark to avoid spoilage.
  • Vulnerable to irradiation, alkalies, acids and oxidizing agents.

Metabolism of Vitamin K

  • Vitamin K is essential for the formation of prothrombin, the blood plasma protein required for blood clotting.
  • When humans consume Vit K1 found in plants, the intestinal bacteria convert it into Vit K2 for storage.
  • The body loses its power to clot the blood in the absence of this vitamin.
  • Infants may develop haemorrhage due to its deficiency. It could be prevented by taking this vitamin during pregnancy.
  • A deficiency of vitamin K could also cause lower fat absorption in the body and excess fat or lipid excretion.

Importance of Vitamin K

  • Prevent fractures due to osteoporosis and osteopenia.
  • Could prevent liver cancer and reduce fatality due to liver cirrhosis.
  • Reduce vascular calcifications.
  • Reduce the risk of coronary heart disease.
  • May improve insulin sensitivity and increase glucose tolerance.

References

  • What to know about vitamin K-2
  • Vitamin K
  • Asmar, Margueritta & Naoum, Joseph & Arbid, Elias. (2014). Vitamin K Dependent Proteins and the Role of Vitamin K2 in the Modulation of Vascular Calcification: A Review. Oman Medical Journal. 29. 172-177. 10.5001/omj.2014.44.
  • DiNicolantonio, J. J., & Bhutani, J. (2015). The health benefits of vitamin K. Open Heart, 2(1), e000300. https://doi.org/10.1136/openhrt-2015-000300

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